Article ID Journal Published Year Pages File Type
5424153 Surface Science 2010 4 Pages PDF
Abstract
For i=j (εii is hydrostatic) and for a flat surface, we show that the equilibrium surface stress gii corresponds to a surface pressure located mainly at the first monolayer and that the presence of the surface energy γ in the Shuttleworth's equation results from the matter conservation rule. Indeed, γ is an energy calculated per constant unit area while the atomic surface varies with the deformation as (1+εii). The equilibrium surface stress gii present at the surface is parallel to the surface. When gii is positive, this signifies that the surface atoms tend to contract together in the direction i even if the bulk pressure p is zero.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
,