| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5424269 | Surface Science | 2009 | 8 Pages |
Abstract
Photoemission and near edge X-ray absorption fine structure (NEXAFS) spectra show that a mixed monolayer of molecular and dissociated vinyl chloride is formed at 130Â K. The polarization dependence of the NEXAFS indicates that vinyl chloride Ï-bonds with the molecular plane nominally parallel to the surface, while vinyl intermediates Ï-bond at Cr centers with the molecular plane nominally perpendicular to the surface, in agreement with DFT predictions of the adsorption geometries.
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Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Mary A. McKee, Qiang Ma, David R. Mullins, Matthew Neurock, David F. Cox,