Article ID Journal Published Year Pages File Type
5424762 Surface Science 2009 5 Pages PDF
Abstract

We show that three independent derivations of the Shuttleworth equation, arguably the second most important equation in surface physics, are inconsistent with Hermann's mathematical structure of thermodynamics [R. Hermann, Geometry, Physics and Systems, Marcel Dekker Inc., New York, USA, 1973 (Chapter 6)]. The possible implications of this result are discussed.

Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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