Article ID Journal Published Year Pages File Type
5425136 Surface Science 2007 5 Pages PDF
Abstract
Reversible polymerization and depolymerization reactions of fullerene (C60) molecules are induced by tunnel injection of holes from tips of scanning tunneling microscopes similarly to the reactions induced by tunneling electrons. The bi-directional and bi-polar features of the hole-induced and electron-induced reactions can be interpreted by a unified model considering ionic reactions over symmetry-imposed barriers in the [2+2] cyclo-addition and the reverse reactions.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
, , , , ,