Article ID Journal Published Year Pages File Type
5425619 Surface Science 2007 6 Pages PDF
Abstract

The self-assembly of meso-tetra (N-methyl-4-pyridyl) porphyrine tetratosylat (H2TMPyP) on an iodide modified Cu(1 1 1) surface has been studied by means of in situ electrochemical-scanning tunneling microscopy (EC-STM). The I/Cu(1 1 1) surface was found to be a good substrate for the self-assembly of highly ordered layers of porphyrin cations. Furthermore, a reversible structural phase transition within the highly ordered porphyrin layer was observed during variation of the electrode potential, as a consequence of changing electronic properties of the substrate.

Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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