Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5426128 | Surface Science | 2007 | 5 Pages |
Abstract
The nuclear spin conversion of a molecule is the modification of the total nuclear spin I of its equivalent atoms. This phenomenon is observed by measuring the relaxation rate of a gas sample initially prepared with a population of spin isomers far from the equilibrium given by nuclear spin statistics. New experimental data obtained at low pressure show a surface-induced enhancement of the nuclear spin conversion in 13CH3F. Contrary to binary collisions in the gas phase, hitting the surface induces direct conversion. Several mechanisms are proposed.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Marcela Tudorie, Mohamed Khelkhal, Jean Cosléou, Patrice Cacciani,