Article ID Journal Published Year Pages File Type
5426228 Surface Science 2007 5 Pages PDF
Abstract

Transmission electron microscopy (TEM) has been used to study the rutile TiO2 (1 0 0) surface in an oxidizing environment. By changing annealing conditions, TiO2 surfaces with different morphologies are obtained. We report a new centered (2 × 2) surface reconstruction on this surface. Our experimental data indicates that this is a meta-stable, oxygen deficient structure formed as the disordered surface regains its stoichiometry in an oxidizing annealing environment.

Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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