Article ID Journal Published Year Pages File Type
5426600 Surface Science 2006 8 Pages PDF
Abstract

The exact formulation of the kinetic of dimer in hypercubic lattices is developed in the framework of the kinetic lattice gas model. The so-called local evolution rules are used to obtain the hierarchy of equation of motion for the correlation functions where processes like adsorption and desorption are included. The hierarchy of equations are truncated using a mean field (m, n) closures which allows the analytical treatment of the system. A general expression for non-interacting dimer isotherm and two particle correlation functions are obtained in hypercubic lattices.

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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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