Article ID Journal Published Year Pages File Type
5426755 Surface Science 2006 4 Pages PDF
Abstract

We demonstrate that ordered arrays of metal clusters of a few nanometers in size can be fabricated by self-assembly on a range of oxide nanotemplates. Two systems were chosen, FeO/Pt(1 1 1) and Fe3O4, having in common a reconstructed close-packed oxygen surface layer. Deposition of various metal films results in the formation of nanosized clusters arranged according to the surface long-range order. Employing ab-initio calculations we discuss the observed mechanism of site-selective nucleation of the metal nanoclusters. Finally, we discuss the existence of a wide family oxide templates that can be used for self-assembled growth of nanoclusters governed by the same rules.

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Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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