Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5426932 | Journal of Quantitative Spectroscopy and Radiative Transfer | 2018 | 5 Pages |
â¢Several water lines near 790â¯nm, in the 013-000 band of H216O are recorded with comb-locked cavity ring-down saturation spectroscopy.â¢Line positions are determined with an uncertainty of 25â¯kHz (relatively 6.6â¯Ãâ¯10â11), over one order of magnitude more accurate in a previous study.â¢Upper energies of these transitions are determined with an accuracy of 10â6 cmâ1, indicating that the IUPAC-reported energies are inaccurate within 0.001 cmâ1.
Water lines in the infrared are convenient frequency references. We present absolute positions of several H216O ro-vibrational transitions around 790â¯nm using comb-locked cavity ring-down saturation spectroscopy. Lamb dips of 6 water lines with saturation power in the range of 70-130â¯kW/cm2 were observed and the line positions were determined with an accuracy of 25â¯kHz, corresponding to a fractional uncertainty of 6.6â¯Ãâ¯10â11. The present work demonstrates the capability to considerably improve the accuracy of the water line positions in the infrared.
Graphical abstractDownload high-res image (149KB)Download full-size image