Article ID Journal Published Year Pages File Type
5427392 Journal of Quantitative Spectroscopy and Radiative Transfer 2017 8 Pages PDF
Abstract

•Energies and transitions of quartet Rydberg series in S13+ ion are studied. Some states are reported for the first time.•Transition parameters for electric-dipole transitions of quartet Rydberg series in S13+ ion are calculated.•Influences from the relativistic effects and intercombination interactions on line strength in S13+ ion are discussed.

The energy levels and transition parameters of Li-like quartet states 1s2snl and 1s2pnl′ (l=s, p, d; l′=s, p, d, f; n=2-7) pertaining to 4Po and 4Le (L=S, P, D) Rydberg series in S13+ ion are calculated using a multi-configuration Rayleigh-Ritz variation method. Relativistic effects and mass polarization contributions are taken into account by using the first-order perturbation theory. The quantum electrodynamics (QED) effects and higher-order relativistic corrections are considered to obtain accurate energy levels by the screened hydrogenic formula. The transition oscillator strengths, transition rates, and wavelengths of electric-dipole transitions for 1s2sns 4Se-1s2lnl′ 4Po and 1s2snp+1s2pns+1s2pnd 4Po-1s2lnl′ 4Le (L=S, P, D) in S13+ ion are systematically calculated and compared with available reference data. Our calculated results will provide valuable data for related experiments in the future.

Related Topics
Physical Sciences and Engineering Chemistry Spectroscopy
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