Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5427393 | Journal of Quantitative Spectroscopy and Radiative Transfer | 2017 | 6 Pages |
â¢The CO2 absorption continuum is measured by CRDS in the 2.3 µm window.â¢The achieved sensitivity and stability allow measurements at sub-atmospheric pressure.â¢The absorption coefficient is on the order of 3Ã10â8 cmâ1 amagatâ2 near 4350 cmâ1.â¢A good agreement is obtained with previous results at much higher density (20 amagat).
The CO2 absorption continuum near 2.3 µm is determined for a series of sub atmospheric pressures (250-750 Torr) by high sensitivity Cavity Ring Down Spectroscopy. An experimental procedure consisting in injecting successively a gas flow of CO2 and synthetic air, keeping constant the gas pressure in the CRDS cell, has been developed. This procedure insures a high stability of the spectra baseline by avoiding changes of the optical alignment due to pressure changes.The CO2 continuum was obtained as the difference between the CO2 absorption coefficient and a local lines simulation using a Voigt profile truncated at ±25 cmâ1. Following the results of the preceding analysis of the CO2 rovibrational lines (Vasilchenko S et al. J Quant Spectrosc Radiat Transfer 10.1016/j.jqsrt.2016.07.002, a CO2 line list with intensities obtained by variational calculations and empirical line positions was preferred to the HITRAN line list. A quadratic pressure dependence of the absorption continuum is observed, with an average binary absorption coefficient increasing from 2 to 4Ã10â8 cmâ1 amagatâ2 between 4320 and 4380 cmâ1.The obtained continuum is found in good agreement with a previous measurement using much higher densities (20 amagat) and a low resolution grating spectrograph and is consistent with values currently used in the analysis of Venus spectra.