Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5428012 | Journal of Quantitative Spectroscopy and Radiative Transfer | 2015 | 7 Pages |
â¢Line profiles are developed with account of soft and hard collisions.â¢Main types of intermolecular interaction were taken into account.â¢A criterion for the analysis of a spectral line narrowing was proposed.â¢Two types of line narrowing were considered.
Algebraic approximations for line profiles calculated on the basis of quantum-mechanical collision integral kernels for dipole-dipole, dipole-quadrupole, and quadrupole-quadrupole intermolecular interaction potentials were obtained. In derivation of the profiles velocity-changing collisions of molecules with scattering on small and large angles also with the speed-dependence of collision relaxation constants have been taken into account. It was shown that the relative contribution of small-angle collisions into the frequency of elastic velocity-changing collisions is much more pronounced for long-range potentials. A sensitive criterion for analysis of a line narrowing was proposed and tested.