Article ID Journal Published Year Pages File Type
5428081 Journal of Quantitative Spectroscopy and Radiative Transfer 2015 13 Pages PDF
Abstract

•12 lowest levels of ground configuration for Er3+ were calculated.•E2 and M1 transition rates are reported for the ground configuration.•Different strategies to include correlation effects are presented.•The calculations are based on MCDHF and RCI methods.

Atomic energy levels and E2 and M1 transition rates are reported for the [Xe]4f11 ground configuration in Er3+ from relativistic multiconfiguration Dirac-Hartree-Fock and configuration interaction calculations. The Breit transverse interaction and leading QED effects are included as perturbations. Different strategies for describing electron correlation effects are tested and evaluated. The calculated energy levels are compared with experiment and results from semi-empirical methods.

Related Topics
Physical Sciences and Engineering Chemistry Spectroscopy
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