Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5428229 | Journal of Quantitative Spectroscopy and Radiative Transfer | 2014 | 8 Pages |
â¢Sm3+ doped germanotellurite glasses with multi-channel emissions were prepared.â¢High asymmetry and covalent environment has been identified in the glass system.â¢Multi-peak red fluorescence is efficiently extracted from the optical glasses.â¢Quantum efficiency and quantum yield are deduced to be 82.5% and 6.0%.
Sm3+ doped germanotellurite glasses (NZPGT) with maximum phonon energy of 793 cmâ1 have been prepared and characterized. Judd-Ofelt parameters Ωt (t=2, 4, 6) have been calculated to be 3.52Ã10â20, 4.70Ã10â20 and 1.90Ã10â20 cm2, respectively. Large value of Ω2 indicates a high asymmetry and covalent environment around Sm3+ in the glass system. The maximum stimulated emission cross-section of the dominant transition 4G5/2â6H9/2 peaking at 645.0 nm was derived to be 10.00Ã10â22 cm2, predicting that the red fluorescence emission can be efficiently extracted from the optical glasses. The internal quantum efficiency and external quantum yield of 0.4 wt% Sm2O3 doped NZPGT glasses were deduced to be 82.5% and 6.0%, respectively. The results demonstrate that Sm3+ doped NZPGT glasses are a potential candidate for developing tunable visible lasers, compact light sources and solid-state display devices.