Article ID Journal Published Year Pages File Type
5429460 Journal of Quantitative Spectroscopy and Radiative Transfer 2010 12 Pages PDF
Abstract

Using FT spectra (unapodized resolution ~0.0056 cm−1) of the nitrous oxide isotopologue 15N216O, the line positions and intensities have been measured for 511 lines of 8 cold bands and one hot band lying between 5800 and 7600 cm−1. A multispectrum fitting procedure has been used to retrieve line parameters from 5 experimental spectra recorded at different pressures. An absolute wavenumber calibration has been performed using acetylene line positions around 6500 cm−1 and water line positions in the 7100-7300 cm−1 region. The average absolute accuracy of the line parameters obtained in this work has been estimated to be ±0.0005 cm−1 for the line positions, 2-5% for the line intensities depending on the transitions. For each studied band, the vibrational transition dipole moment squared value and the empirical Herman-Wallis coefficients have been determined. Moreover, the line positions measured in this work and those collected from the literature allowed the global fitting of the effective Hamiltonian parameters for this isotopologue.

Related Topics
Physical Sciences and Engineering Chemistry Spectroscopy
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