Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5429563 | Journal of Quantitative Spectroscopy and Radiative Transfer | 2010 | 6 Pages |
Abstract
In this article, we present a new technique for determining the transition probabilities per collision using a set of transition rates per unit time. The problem is solved by introducing a normalization function, which is readily found from a recursion equation for the case of separable kernels. A classical approach to rotation of molecules allows the line-broadening coefficients, the moments of energy transfer, and the mean number of collisions to be calculated analytically in terms of the exponential energy-gap law.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Spectroscopy
Authors
M.L. Strekalov,