Article ID Journal Published Year Pages File Type
5429563 Journal of Quantitative Spectroscopy and Radiative Transfer 2010 6 Pages PDF
Abstract
In this article, we present a new technique for determining the transition probabilities per collision using a set of transition rates per unit time. The problem is solved by introducing a normalization function, which is readily found from a recursion equation for the case of separable kernels. A classical approach to rotation of molecules allows the line-broadening coefficients, the moments of energy transfer, and the mean number of collisions to be calculated analytically in terms of the exponential energy-gap law.
Related Topics
Physical Sciences and Engineering Chemistry Spectroscopy
Authors
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