Article ID Journal Published Year Pages File Type
5430213 Journal of Quantitative Spectroscopy and Radiative Transfer 2009 13 Pages PDF
Abstract

The high resolution absorption spectrum of methane has been recorded at liquid nitrogen temperature by direct absorption spectroscopy between 1.36 and 1.30 μm (7351-7655 cm−1) using a cryogenic cell and a series of distributed feed back (DFB) diode lasers. The investigated spectral range corresponds to the high energy part of the icosad dominated by the ν2+2ν3 band near 7510 cm−1. The positions and strengths at 81 K of 3473 transitions were obtained from the spectrum analysis. The minimum value of the measured line intensities (at 81 K) is on the order of 10−26 cm/molecule, i.e. significantly lower than the intensity cut off of the HITRAN database in the region (4×10−25 cm/molecule at 296 K). From the variation of the line strength between 81 and 296 K, the low energy values of 1273 transitions could be determined. They represent 69% and 81% of the absorbance in the region at 296 and 81 K, respectively. The obtained results are discussed in relation with the few rovibrational assignments previously reported in the region.

Related Topics
Physical Sciences and Engineering Chemistry Spectroscopy
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