Article ID Journal Published Year Pages File Type
5430421 Journal of Quantitative Spectroscopy and Radiative Transfer 2007 15 Pages PDF
Abstract

The absorption spectrum of N2O, at room temperature, was recorded in the 5400-11 000 cm-1 region at resolutions ranging from 0.008 cm-1 near 5400 to 0.023 cm-1 near 11 000 cm-1 using a Bruker IFS120HR Fourier transform spectrometer. Sample pressure/absorption path length products ranging from 200 to 4700 mbar×m were used. More than 6000 absolute line intensities have been measured in 64 different bands of 14N216O. Using wavefunctions previously determined from a global fit of an effective Hamiltonian to more than 18 000 line positions [Tashkun SA, Perevalov VI, and Teffo JL, to be published], the experimental intensities measured in this work and by Toth [J Mol Spectrosc 1999;197:158-87] were fit using 62 parameters of a corresponding effective dipole moment, with residuals very close to the experimental uncertainty.

Related Topics
Physical Sciences and Engineering Chemistry Spectroscopy
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