Article ID Journal Published Year Pages File Type
5430767 Journal of Quantitative Spectroscopy and Radiative Transfer 2008 7 Pages PDF
Abstract

The air induced broadening coefficients of the pure rotational transitions of H2O at 556.936 GHz (110←101), and 752.033 GHz (211←202) were measured by terahertz time-domain spectroscopy. The air broadening coefficient was determined to be 4.012(30)MHzTorr-1 for the 556.936 GHz line and 3.964(40)MHzTorr-1 for the 752.033 GHz line, respectively. The present broadening coefficients for the 556.936 GHz water line are significantly smaller than those of Markov and Krupnov [Measurements of the pressure shift of the 1(10)-1(01) water line at 556.936 GHz produced by mixtures of gases. J Mol Spect 1995:172;211-4] but relatively close to the values of the HITRAN database. The measured data may improve the accuracy of the abundance of water vapor retrieved from spectra obtained by the Odin/SMR satellite instrument. The effect on the satellite retrieval processing is discussed.

Related Topics
Physical Sciences and Engineering Chemistry Spectroscopy
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