| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5432153 | Carbon | 2017 | 5 Pages |
Due to its semi-metallic characteristics, graphene may allow electron transfer to take place between itself and electrically-contacted metals. Here, we discover a two-component (graphene and copper) and two-process (ion migration and electron transfer) cycle, in which (a) electrons travel from the copper substrate to graphene based on Fermi-level variations through the interface, and (b) ions migrate vice versa due to Coulomb force via the intercalated electrolyte. To validate this proposed cycle, we scrutinize the copper-oxide formation, graphene-lattice phonon-frequency variations, and the morphological evolution of copper oxides, primarily via Raman measurements. Our study may provide the guidance for fundamental research on other graphene-metal assemblies as well as may enhance the versatility of graphene-based applications.
Graphical abstractElectrons transfer between graphene and electrically-contacted metals because of the former's semi-metallic characteristics. We discover a cycle comprising two components (graphene and copper) and two processes (ion migration and electron transfer). In this cycle, electrons travel from the copper to graphene based on Fermi-level variations, and ions migrate reversely via the intercalated electrolyte. To validate this proposed cycle, we investigate first the copper-oxide formation, then graphene-lattice phonon-frequency variations, and finally the morphological evolution of copper oxides via Raman and SEM measurements. Our study offers a guide for basic research on graphene-metal assemblies and broadens graphene-based applications.Download high-res image (270KB)Download full-size image
