Article ID Journal Published Year Pages File Type
5434881 Materials Science and Engineering: C 2017 8 Pages PDF
Abstract

•Experimental characterization of PVA hydrogels•Immersed mechanical testing in a thermo-regulated solution•Mechanical response to a load case of hydrogels synthetized using different elaboration parameters•Hyper-elastic modeling of the material response of the PVA hydrogel•Deduction of the density of macro-molecular chains from the mechanical response

This paper investigates the influence of three different processing parameters on the global mechanical behavior of PVA (Polyvinyl alcohol)/DMSO (Dimethylsulfoxide) hydrogels: the initial concentration of PVA, the DMSO:H2O ratio and the number of freeze/thaw cycle applied to the material. A specific thermo-regulated testing apparatus for hydrophilic materials is presented, along with the performed cyclic and rupture tests. The observed mechanical responses are explained by an in-depth analysis of the cross-linking phenomenon. Using the Neo-Hookean hyperelastic model, the experimental data is fitted and a link between the density of macro-molecular chains in the material and its mechanical behavior is established. Strong differences are observed and discussed.

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