Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5435326 | Synthetic Metals | 2017 | 7 Pages |
â¢Polyethylene oxides in electropolymerization forming more compact PPy films.â¢Linear actuators of PPy-PEO/DBS showing significant increase in strain.â¢The ion diffusion coefficient and strain rate is improved in PPy-PEO/DBS.
In the present paper, we report the electro-chemo-mechanical deformation (ECMD) measurements of pristine polypyrrole (PPy) and polypyrrole/poly(ethylene oxide) composite films doped with dodecylbenzenesulfonate (DBS) under isotonic (constant force) conditions. The PPy/DBS and PPy-PEO/DBS films, the latter made from a polymerization solution containing 5Â wt% PEO, were actuated potentiodynamically in an aqueous solution containing lithium bis-trifluoromethane-sulfonimide (LiTFSI). The obtained composite films were characterized with scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectroscopy and Fourier transform infrared spectroscopy (FTIR). The results confirmed the successful incorporation of PEO within the PPy film. The composite films showed a remarkable improvement in maximum strain achieved (of 7.7%), nearly double that of the pristine PPy/DBS film, had a higher conductivity, higher ion diffusion coefficient and faster strain rate. The ECMD measurements for both the pristine as well as the PEO-composite films showed cation driven actuation involving the migration of Li+ cations in the aqueous electrolyte.