Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5437531 | Ceramics International | 2017 | 10 Pages |
Abstract
The influence of the A-site cation size-disorder Ï2 on the structural and magnetic properties of the polycrystalline Pr0.4Re0.1Sr0.5âyBayMnO3 (Re = Pr, Sm, Eu, Gd, Dy and Ho) samples with a constant average ionic radius = 1.2445Â Ã
, is investigated. All samples were synthesized using the solid-state reaction. Rietveld refinement of the X-ray diffraction patterns shows that the substitution generates a structural transition from tetragonal to orthorhombic symmetry. The temperature dependence of magnetization indicates a weakening of ferromagnetism by the increase of Ï2. The large difference between the field cooled and zero field cooled magnetization below Curie temperature suggests the presence of an inhomogeneous mixture of a ferromagnetic and antiferromagnetic domains at low temperature. The maximum of the magnetic entropy change decreases with increasing the mismatch effect. However, several peculiarities were observed in the magnetic behavior indicating that Ï2 is not the only factor controlling the physical properties; the nature and the magnetic moment of the substituent should be taken in consideration.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
M. Bourouina, A. Krichene, N. Chniba Boudjada, W. Boujelben,