Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5438094 | Ceramics International | 2017 | 19 Pages |
Abstract
Nitrogen-doped carbon-coated Li4Ti5O12-TiO2 (LTO-TO) hybrid microspheres were prepared by heat treating the dry mixture of urea and chemically lithiated dandelion-like TiO2 microspheres in a stainless steel autoclave at 550 °C for 5 h. The hybrid materials were tested as anode of Li-ion batteries. As compared to the pristine sample, the N-doped carbon-coated LTO-TO microspheres exhibited higher specific capacity at both low and high current rates. Discharge capacities of 184 and 123 mAh gâ1 were obtained at 0.2 C and 20 C, respectively. Moreover, the LTO-TO/C electrode showed excellent cycle performance, with a discharge capacity of 121.3 mAh gâ1 remained after 300 cycles at 5 C, corresponding to an average capacity degradation rate of 0.073% per cycle. These high specific capacity, excellent rate capability and cycle performance demonstrated the high potentiality of the N-doped carbon-coated LTO-TO microspheres as anode material of both energy storage-type and power-type Li-ion batteries.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Chunhai Jiang, Shangbiao Liu, Qinghuang Lian, Jing Zhao, Weiqiang Ding, Zhiyang Yu, Renzhong Huang, Zhimin Zou,