Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5438115 | Ceramics International | 2017 | 29 Pages |
Abstract
In this paper, LiTi2(PO4)3@carbon/graphene (LCG) hybrid was prepared and investigated as anode for aqueous lithium ion batteries (ALIBs). The as-prepared hybrid was characterized by XRD, SEM, TEM and TGA. The electrochemical performances of nano-structured materials as anode were evaluated by cyclic voltammetry, electrochemical impedance spectroscopy and charge-discharge tests. The cell using LCG as anode exhibits excellent cycling performance both at relatively low and high rates. The capacity retention of LCG can remain 87.6% at 0.2 C after 200 cycles and 77.2% at 5 C after 1000 cycles compared with LiTi2(PO4)3@carbon (0.2 C: 71.8%, 5 C: 58.1%). Moreover, LCG reveals superior rate capability with 80.8 mA h gâ1, 62.1 mA h gâ1 at 10 C and 20 C, respectively. The outstanding electrochemical performance of LCG comes from the improved electrical conductivity and the forming of efficient conductive network. The results demonstrate that the graphene-modified LiTi2(PO4)3@carbon is a promising anode for ALIBs.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Zhi Zhou, Wei Luo, Hao Huang, Shengxiong Huang, Yongji Xia, Nan Zhou, Zhangxing He,