Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5438584 | Ceramics International | 2017 | 29 Pages |
Abstract
In this work, Li5Cr7Ti6O25 as a new anode material for rechargeable batteries is fabricated through a simple sol-gel method at different calcination temperatures. The X-ray diffraction, scanning electron microscopy, high resolution transmission electron microscopy, charge/discharge curve and cyclic voltammograms are utilized to study the crystal structures, morphologies and electrochemical properties of as-obtained Li5Cr7Ti6O25 samples. The impact of calcination temperatures on morphologies and electrochemical properties of Li5Cr7Ti6O25 is discussed in detail. The test result shows that the 800 °C is a proper calcination temperature for Li5Cr7Ti6O25 with excellent electrochemical properties. Cycled at 200 mA gâ1, it displays a high initial reversible capacity of 146.6 mA h gâ1 and retains a considerable capacity of 130.8 mA h gâ1 after 300 cycles. Even cycled at large current density of 500 mA gâ1, the initial reversible capacity of 129.6 mA h gâ1 with the capacity retention of 88% after 300 cycles is achieved, which is obviously higher than that of Li5Cr7Ti6O25 prepared at 700 °C (80.5 mA h gâ1 and 68%) and 900 °C (98.4 mA h gâ1 and 80%). In addition, in-situ XRD analysis reveals that Li5Cr7Ti6O25 exhibits a reversible structural change during lithiation and delithiation processes. The above prominent electrochemical performance indicates the great potential of the Li5Cr7Ti6O25 obtained at 800 °C as anode material for rechargeable batteries.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Shan Liu, Lei Yan, Hua Lan, Haoxiang Yu, Shangshu Qian, Xing Cheng, Nengbing Long, Miao Shui, Jie Shu,