Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5438897 | Ceramics International | 2017 | 36 Pages |
Abstract
This paper describes the synthesis of a new series of g-C3N4/Nb2O5 heterostructures and their application in the removal of organic pollutants from water, as a combined strategy of photocatalysis and adsorption processes. The heterostructures were synthesized at different weight ratios through thermal oxidation and hydrothermal treatment, leading to an uniform assembly of Nb2O5 nanoparticles onto g-C3N4 surface. The heterostructures exhibited improved textural and electronic properties (narrowing in band gap) when compared to pure g-C3N4 and Nb2O5, respectively. Although adsorption capacities were shown to be influenced by Nb2O5 content, g-C3N4 was essential to increase the photocatalytic response of the g-C3N4/Nb2O5 heterostructures, which displayed an enhancement of photocatalytic performance on the degradation of methylene blue and rhodamine B dyes under visible and ultraviolet irradiation. The enhanced photoactivity was explained by the increase in the lifetime of the charge carries due to formation of heterojunctions between Nb2O5 and g-C3N4. A mechanistic investigation on the photocatalytic process was conducted by using different reactive scavenger species. The superoxide (O2â
- ) radical was found to be the main active specie on the dye photodegradation activated by visible radiation.
- ) radical was found to be the main active specie on the dye photodegradation activated by visible radiation.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Kele T.G. Carvalho, André E. Nogueira, Osmando F. Lopes, Gabriela Byzynski, Caue Ribeiro,