Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5439947 | Corrosion Science | 2017 | 10 Pages |
Abstract
We present results of a Ni superalloy oxidized for short times in high purity CO2 and similarly in Ar containing â¤Â 1 ppb O2. A detailed analysis of the oxidized surfaces reveals striking similarities for the two exposure environments, suggesting O2 impurities control the oxidation process in high-temperature CO2. Selective oxidation results in Cr-rich oxide layers grown by outward diffusion, while Cr vacancies left in the metal contribute to significant void formation at the oxide/metal interface. Unlike for most of the alloy surface, the oxidation behavior of secondary phase metal carbides is considerably different in the two environments.
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Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Richard P. Oleksak, John P. Baltrus, Jinichiro Nakano, Anna Nakano, Gordon R. Holcomb, Ãmer N. DoÄan,