Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5440250 | Journal of the European Ceramic Society | 2018 | 30 Pages |
Abstract
A series of experiments were performed to study the solid solubility of CaO in BaY2O4, and the observed results were then adopted to the present thermodynamic evaluation to derive a set of thermodynamic database for the BaO-CaO-YO1.5 system. The database was constructed by the CALPHAD method where the binary parameters from the BaO-CaO and CaO-YO1.5 systems were presently optimized, those from the BaO-YO1.5 system were simulated by our previous assessments, and only limited amount of ternary parameters were introduced. All the model parameters were emanated from the Bragg-Williams approximation where the liquid and terminal solid-solution phases were treated by the one-sublattice model, and two ternary intermediate phases, named BCY (BaCa2Y6O12) and BaY2O4, were described by the three-sublattice and two-sublattice models, respectively. Good agreement between the experimental data and the calculated results demonstrates that the present thermodynamic database is self-consistent and credible and able to be used to design novel refractory.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Zhu Li, Jing Wang, Baotong Li, Shusen Wang, Wajid Ali, Shihua Wang, Xueguang Wang, Xionggang Lu, Chonghe Li, Kun Wang,