Article ID Journal Published Year Pages File Type
5442960 Optical Materials 2016 4 Pages PDF
Abstract
The optical and scintillation properties of Cs3BiCl6 single crystals were characterized, and absorption properties were investigated for thin films. The thin films showed two absorption bands at ∼220 nm and 330 nm; these bands can be attributed to the 1A1g → 1T1u and 1A1g → 3T1u transitions of Bi3+ ions, respectively. A luminescence band was observed at ∼390 nm in the photoluminescence spectra; this band can be attributed to the 3T1u → 1A1g transition of Bi3+ ions. In the X-ray-induced radioluminescence spectrum, in addition to the luminescence band at 390 nm, another band was observed at 600-700 nm; this band was tentatively attributed to the radiative recombination of self-trapped excitons. The decay-time constants of photoluminescence and scintillation decay were of the order of nanoseconds. The scintillation light yield was 800 photons/MeV. The results indicate that Cs3BiCl6 has a fast scintillation decay and a relatively poor light yield.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
Authors
, , , , , ,