Article ID Journal Published Year Pages File Type
5447319 Journal of Physics and Chemistry of Solids 2017 25 Pages PDF
Abstract
Sputter-deposited Sb2S3 thin films were studied to understand the role of the initial film deposition temperature on the subsequent crystallization during the post-annealing in N2-S ambient. The films were deposited with substrate temperatures in the range 200-350 °C. The as-deposited films were amorphous independent of the substrate temperature, however, after annealing at 300 °C all the films turned in to polycrystalline. It was observed that the thermal history (deposition temperature) of the films have a notable influence on the crystallization and grain growth due to post-annealing at 300 °C. The material properties of the annealed film such as: crystallite size, strain, grain size, refractive index, and film stoichiometry showed a dependence on the original film deposition temperature. Furthermore, AFM and SEM micrographs revealed a direct dependence of the morphological features such as grain growth, uniformity and compactness on the thermal history. Studies by variable-angle spectroscopic ellipsometry (VASE) provided some optical parameters including inter-band transitions in the Sb2S3 thin films. We present the parameterization of the dielectric function of Sb2S3 using a multi-oscillator model composed by one Tauc-Lorentz and three Lorentz oscillators.
Related Topics
Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
Authors
, , , ,