Article ID Journal Published Year Pages File Type
5448633 Materials Science and Engineering: B 2017 8 Pages PDF
Abstract
In this study, starch was added to the delafossite CuAl0.9Fe0.1O2 with the purpose of creating porosity in the structure. Increasing porosity contributes to a decrease in thermal conductivity, which increases the figure of merit (ZT) for thermoelectric properties. The results show that the porosity of the material increased as starch content was raised from 0 to 3 wt%. The thermal conductivity of CuAl0.9Fe0.1O2 at room temperature decreased from 9.12 to 5.44 W/m.K as porosity increased from 12.0 to 43.4 vol%. The electrical conductivity decreased with increasing starch concentration, with the values ranging from 0.32 to 0.08 S/cm. Of all samples from 0 to 3 wt% starch, the sample with 1 wt% showed the highest ZT value. The increase of the ZT value resulted in a decrease in thermal conductivity due to sample porosity.
Related Topics
Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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