Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5451000 | Solar Energy | 2017 | 7 Pages |
Abstract
Cu2ZnSn(S,Se)4 (CZTSSe) thin films with controlled composition, phase, and uniformity were fabricated by sulfo-selenization of stack layer electro-deposited Cu-Sn-Zn precursors. In order to reduce the detrimental bubble phenomenon, Triton X-100 surfactant assisted deposition of the zinc layer was conducted. The effects of Triton X-100 addition on the surface morphology, composition, and solar cell properties were investigated. The results indicated that the addition of Triton X-100 boosted the solar cell performance by many folds. Along with studying the effect of Triton X-100 addition, the composition of the film was finely controlled by varying the deposition time of the Cu layer. Cu poor and Zn rich composition with a Cu/(Zn + Sn) ratio of 0.82 was achieved. The prepared films were characterized by X-ray diffraction, scanning electron microscopy, X-ray fluorescence spectroscopy, and Raman spectroscopy to investigate the structural, morphological, and compositional properties. The highest solar cell performance of approximately 6.06% was achieved for the film in which the Cu-layer was deposited for 15 min.
Keywords
Related Topics
Physical Sciences and Engineering
Energy
Renewable Energy, Sustainability and the Environment
Authors
Yoon Jin Kim, Eun Jin Jo, Archana S. Kamble, Myeng Gil Gang, Jun Ho Kim, Jong Ha Moon, Jin Hyeok Kim,