Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5458435 | Journal of Alloys and Compounds | 2017 | 8 Pages |
Abstract
We prepared a three-dimensional (3D) hybrid structure by assembling dense gold nanoparticles (Au NPs) on graphene supported on electron beam lithography-fabricated silver nanodisk arrays (Ag NDAs). Using the strategy of modulating the structure parameters via EBL system to sufficiently narrow the distances between adjacent disks, we successfully constructed sub-10-nm gaps between the horizontally patterned Ag NDs. Moreover, uniform nanometer-scale graphene gaps were obtained between Au NPs and Ag NDAs. Finite element numerical simulations revealed that the multi-dimensional plasmonic couplings in the 3D Au NP-graphene-Ag NDA system led to an electric field enhancement up to 112 times in graphene defined gaps. As demonstrated by our SERS measurements, the well-designed and fabricated 3D Au NP-graphene-Ag NDA hybrid structure exhibits 3200-fold enhancement of the Raman response of graphene, and sensitive SERS detection with a limit of 0.1 pM for crystal violet molecules, which can be attributed to the extremely strong electric field enhancement and chemical enhancement of graphene. This work represents a step towards high-sensitivity and strong-reproducibility SERS substrate fabrication, and opens a new avenue for rationally designing graphene-plasmonic hybrid structures for SERS sensing.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Yuan Zhao, Xiyu Li, Meishan Wang, Lichun Zhang, Binhua Chu, Chuanlu Yang, Yu Liu, Dianfa Zhou, Yalin Lu,