Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5459191 | Journal of Alloys and Compounds | 2017 | 36 Pages |
Abstract
In this work, flower-like hierarchical Nb2O5 microspheres self-assembled by nanorod with orthorhombic (T) phase were synthesized using hydrothermal method. The structure and morphology of T-Nb2O5 prepared is characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The structure and morphology evolution mechanisms have been preliminarily proposed for the flower-like hierarchical structure. The electrochemical performances of T-Nb2O5 electrodes synthesized are detailed studied for use in LIBs and HSC devices. The T-Nb2O5 anode exhibits the reversible capacity of 191.42 mA h gâ1 at 0.05 A gâ1 and excellent rate performance (90.01 mA h gâ1 at 5A gâ1) in the voltage of 1.1-3.0 V (vs Li/Li+). The HSC using T-Nb2O5 anode and activated carbon cathode device delivers outstanding power density and energy density (8750 W kgâ1 and 40.25 W h kgâ1) with good stability in the voltage of 0.5-3.0 V.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Jing Zhai, Yanbo Wu, Xiaomin Zhao, Qizhi Yang,