Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5459370 | Journal of Alloys and Compounds | 2017 | 7 Pages |
Abstract
α-MoO3 is a well-investigated layer-structured material for intercalation of different ions. Here, for the first time, we utilized Be2+ electrolyte for electrochemical characterization of α-MoO3 for supercapacitor applications. Our studies revealed a minimized detrimental effect of proton (H+) co-intercalation at a high current density 25 Agâ1 resulting in excellent cyclability with a specific capacitance of 169 Fgâ1 and a retention of 81% capacitance after 2000 cycles. The electrochemical impedance and ionic diffusion measurements reflected a reduced intercalation of H+ and higher diffusion coefficient of Be2+ as the contributing factors for unusually high and stable capacitance of MoO3 at high current density.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Juan C. Icaza, Ramesh K. Guduru,