Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5460178 | Journal of Alloys and Compounds | 2017 | 44 Pages |
Abstract
In the present study the effect of preparation conditions on microstructure and electrical properties of MgTiO3 ceramics was investigated. Mixture of MgO and TiO2 powders was subjected to mechanical activation for different time periods. Two types of sintering (two-step and HIP sintering) were performed on green bodies prepared by cold isostatic pressing. AC impedance spectroscopy in the low-frequency range (from 20Â Hz to 1Â MHz), at room and elevated temperatures, were performed in order to separate contribution of grains and grain boundaries to capacitance, resistance and conductivity of magnesium titanate ceramics. The special attention was directed to explanation of the influence of mechanical activation on electrical and morphological changes in sintered samples. The significant decrease of partial oxygen pressure in HP sintering atmosphere caused the change from insulating behavior of MgTiO3 samples after two-step sintering to semiconducting one.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
S. FilipoviÄ, V.P. PavloviÄ, N. ObradoviÄ, V. PaunoviÄ, K. Maca, V.B. PavloviÄ,