Article ID Journal Published Year Pages File Type
5460761 Journal of Alloys and Compounds 2017 6 Pages PDF
Abstract
The influence of solidification history on unstressed long-term microstructure stability of TCP in completely heat-treated Mo-rich Ni3Al based single crystal superalloys with cellular and dendritic as-cast microstructures was studied by experimental analysis and the thermodynamic calculation (by JMatPro). High temperature solution treatment can completely eliminate microsegregation of alloying elements in both as-cast cellular and dendritic samples, whereas, the influence of as-cast microstructure (solidification history) on the composition of γ phase cannot be eliminated by solution treatment: Mo, Cr and Re contents of γ phases in as-cast and heat-treated dendritic samples were both higher than those in cellular samples. Meanwhile, as compared with heat-treated cellular sample, higher area fraction of TCP phase in heat-treated dendritic sample was due to higher supersaturation degree of γ phase, rather than the difference in the microsegregation behavior of alloying elements. Even so, TCP phases in both long-term aged cellular and dendritic samples were found to be Mo-, Cr- and Re-rich P phases with close compositions.
Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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