Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5460977 | Journal of Alloys and Compounds | 2017 | 35 Pages |
Abstract
The magnetic properties and magnetic structure of an as-prepared Mn(Co0.96Fe0.04)Ge sample has been investigated by powder neutron diffraction as well as X-ray diffraction and magnetisation measurements. The sample has a ferromagnetic structure in the low-temperature orthorhombic phase and a magneto-structural transition at 299 (1) K to the high-temperature paramagnetic hexagonal phase. This transition occurs at a higher temperature than for as-prepared (Mn0.96Fe0.04)CoGe (TM = 239 (1) K). Increased occupancy by Fe of the Co (4c) site rather than the Mn (4c) site results in this smaller suppression of the structural transition temperature away from that of undoped MnCoGe. It was found that chemical pressure increased the Curie temperature TCorth in the orthorhombic phase from 355 (5) K in Mn(Co0.96Fe0.04)Ge to 379 (6) K in MnCoGe. Mn(Co0.96Fe0.04)Ge exhibits a large magnetocaloric effect around the magneto-structural transition, âÎSmpeak = 11 (2) J kgâ1 Kâ1 and RC = 187 (30) J kgâ1 with μ0ÎH = 5 T. The magneto-structural transition is a first order transition as demonstrated by master curve analysis.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Q.Y. Ren, W.D. Hutchison, J.L. Wang, A.J. Studer, S.J. Campbell,