Article ID Journal Published Year Pages File Type
5463470 Materials Letters 2017 14 Pages PDF
Abstract
Hexagonal CaAl2Si2O8 was precipitated inside of 25CaO-20Al2O3-55SiO2 (wt%) glass by heat treatment at 1050 °C with MoO3 and carbon as nucleating agents. Transmission electron microscopy revealed that metallic molybdenum particles with sizes of ∼200 nm precipitated in the glass and served as heterogeneous nucleation sites for plane-like hexagonal CaAl2Si2O8 crystals with widths greater than 10 μm and thicknesses of ∼1 μm. The thickness direction was the c-axis of hexagonal CaAl2Si2O8.
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Physical Sciences and Engineering Materials Science Nanotechnology
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