Article ID Journal Published Year Pages File Type
5464785 Surface and Coatings Technology 2017 7 Pages PDF
Abstract
After oxidation at 800 °C for 1000 h, both the Cr2N and (Cr,W)2N coatings had bilayer scales comprising Cr2O3 and (Mn,Cr)3O4. The Cr2N and (Cr,W)2N coatings exhibited similar oxidation curves and a two stages of oxidation mechanism. The main reason for the occurrence of the dominant oxidation mechanism transfer is the growth of Cr2O3 and (Mn,Cr) 3O4 spinel. Moreover, the doping of W benefited the formation of a χ phase to precipitate at the oxide/coating interface, which acted as a diffusion barrier retarding the reaction rate between Cr and O.
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Physical Sciences and Engineering Materials Science Nanotechnology
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