Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5468340 | Vacuum | 2017 | 7 Pages |
Abstract
The contribution deals with transparent conductive oxides based on ZnO, which were prepared by Pulsed Laser Deposition (PLD) and their different properties are compared in the scope of the applied ablating lasers: (1) a solid state Nd:YAG laser working at third harmonic generation (wavelength 355Â nm, 15 ns pulse length and 10Â Hz pulsing frequency) and (2) an excimer laser working with KrF gas composition (248Â nm, 20 ns and 10Â Hz). The first part of the study deals with the influence of the oxygen pressure on crystallographic parameters of undoped ZnO films and the pressure interval between 2 and 5Â Pa was assessed as an optimum. Moreover, the influence of different doping elements, aluminum and gallium, respectively, were analyzed. The results showed that a small amount (â¼0.15% wt. content) of Al (or Ga, respectively) substantially improved carrier concentration with adequate resistivity decrease. Furthermore, optical properties: - transmittances and energy band-gap shift were investigated. Comparison between applied lasers revealed a substantially positive effect on electrical properties for the excimer laser. Moreover, acquired results showed that there is a complex dependence among chemical composition, growth conditions and final properties of the ZnO doped films which can be effectively controlled by using PLD.
Related Topics
Physical Sciences and Engineering
Materials Science
Surfaces, Coatings and Films
Authors
Jaroslav Bruncko, Pavol Å utta, Marie Netrvalová, Miroslav Michalka, Andrej Vincze, Jaroslav jr.,