Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5479820 | Journal of Cleaner Production | 2017 | 11 Pages |
â¢Activated carbons (ACs) is prepared from Ironwood biomass by chemical activation with H3PO4 and KOH.â¢AC by KOH chemical activation illustrated enhanced CO2 loading relative to the commercial activated carbon (CAC).â¢Specific surface area and micropore volume of ACs had a significant effect on the amount of CO2 uptake.â¢The scale-up potential of synthesized AC from Ironwood biomass was investigated.
The adsorption capacity of CO2 and the economic estimation of synthesized activated carbons (ACs) from Persian Ironwood biomass were evaluated in the present study. In addition, the effect of different impregnation ratios of activation agents, including KOH and H3PO4, and various carbonization temperatures on the properties of synthesized ACs was examined by different analyses. The obtained results revealed that BET surface area (SBET) and micropore volume of synthesized ACs were enhanced with an increase in the impregnation ratio of the precursor to KOH. Moreover, the synthesized AC by KOH activation with an impregnation ratio of 1:3 (precursor: activating agent), and a carbonization temperature of 1073Â K demonstrated the higher SBET (1935.8Â m2/g), micropore volume percentage (about 98%), and CO2 adsorption (5.05Â mmol/g) at 1Â bar and 303Â K. Considering the thermodynamic parameters, the dominant mechanism for CO2 uptake was physisorption, spontaneous, and exothermic in nature. Furthermore, based on the annual production of 900,000Â kg, the estimated capital costs for AC by KOH activation and AC by H3PO4 activation would be $1.65 and $1.58 per kg, respectively.
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