Article ID Journal Published Year Pages File Type
56309 Catalysis Today 2011 7 Pages PDF
Abstract

Calcium hydroxyapatites (Hap) solids were prepared with various Ca/P atomic ratios, leading to stoichiometric Ca10(PO4)6(OH)2, calcium-deficient (Ca/P < 1.67) and calcium-rich materials. Their acid/base properties were tailored by the introduction of sodium and/or carbonate entities. The various hydroxyapatite solids were characterized by chemical analysis, IR, XRD and TGA techniques, and tested in methanol thiolation. The acid/base properties were evaluated using the isopropanol decomposition as a test reaction. Catalytic performances were found to be related to their acid/base properties. Total methanol conversion at 400 °C with high selectivity in methanethiol (60%) was obtained for the Na-CO3 modified Hap.

Related Topics
Physical Sciences and Engineering Chemical Engineering Catalysis
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