Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
56312 | Catalysis Today | 2011 | 4 Pages |
Abstract
KF/γ-alumina is an effective catalyst for the aldol condensation of citral with acetone. Even at a relatively low acetone/citral ratio of 1–10, the selectivity to pseudoionones was high, ranging between 82% and 97%. X-ray diffraction shows the presence of KF and K3AlF6 crystallographic phases on the supported catalyst. At KF loadings of 3–6.75 mmol g−1, a pretreatment of the catalyst by heating to 450 °C was necessary to obtain an active catalyst. However, samples with KF loadings of 8.5 mmol g−1 and higher were active even without pretreatment, facilitating handling and use of the catalysts. The development of (1 1 1) planes revealed by in situ XRD during the thermal activation process correlates with the activity for aldol condensation.
Keywords
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Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Vadikukarasi Raju, Rajitha Radhakrishnan, Stephan Jaenicke, Gaik Khuan Chuah,