| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 57256 | Catalysis Today | 2009 | 6 Pages |
Abstract
Chelating dicarbene palladium(II) complexes have been found to catalyse the hydroarylation of alkynes with excellent conversions and selectivities at low catalyst loading (0.1 mol.%). Products of formal trans hydroarylation of the triple bond are formed in high yields. Optimisation of the reaction parameters (nature of the solvent system, concentration of the reagents, reaction temperature) allows to further increase the selectivity of the reaction under mild reaction conditions.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Gabriella Buscemi, Andrea Biffis, Cristina Tubaro, Marino Basato,