Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5783260 | Geochimica et Cosmochimica Acta | 2017 | 43 Pages |
Abstract
Our results provide insights into Ca isotope fractionation in high-temperature geochemical processes. Given that Ca content x in opx from natural peridotites is usually lower than 1/32 and Fe content y is generally â¼10 mol%, Ca and Fe concentration effects on 103lnαopx-cpx in natural samples are negligible. Rather, 103lnαopx-cpx is mainly controlled by temperature. 103lnαopx-cpx of 44Ca/40Ca decreases from 0.50â° to 0.26â° when temperature increases from 1000 K to 1400 K if the Fe effect is taken into account. Therefore, if Ca isotope fractionation between opx and cpx (Î44/40Caopx-cpx) in natural peridotites is greater than 0.50â° or lower than 0.26â°, it may indicate disequilibrium of Ca isotopes. Finally, the large 103lnαopx-cpx relative to our current analytical precision suggests that Î44/40Caopx-cpx can be used as an independent thermometer with a precision comparable to elemental thermometers. Because most naturally occurring minerals are solid solutions with variable chemical compositions, this study presents a guideline to explore the concentration effect on equilibrium isotope fractionation among minerals.
Related Topics
Physical Sciences and Engineering
Earth and Planetary Sciences
Geochemistry and Petrology
Authors
Wenzhong Wang, Chen Zhou, Tian Qin, Jin-Ting Kang, Shichun Huang, Zhongqing Wu, Fang Huang,