Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
579981 | Journal of Hazardous Materials | 2010 | 6 Pages |
Abstract
Present paper studies the influence of electrochemically generated mixed oxidants on the physicochemical properties of natural organic matter, and especially from the disinfection by-products formation point of view. The study was carried out in a full scale water treatment plant. Results indicate that mixed oxidants favor humic to non-humic conversion of natural organic matter. Primary treatment preferentially removes the more hydrophobic fraction. This converted the non-humic fraction in an important source of disinfection by-products with a 20% contribution to the final trihalomethane formation potential (THMFPF) of the finished water. Enhanced coagulation at 40 mg lâ1 of polyaluminium chloride with a moderate mixing intensity (80 rpm) and pH of 6.0 units doubled the removal efficiency of THMFPF achieved at full scale plant. However, gel permeation chromatography data revealed that low molecular weight fractions were still hardly removed. Addition of small amounts of powdered activated carbon, 50 mg lâ1, allowed reduction of coagulant dose by 50% whereas removal of THMFPF was maintained or even increased. In systems where mixed oxidants are used addition of powdered activated carbon allows complementary benefits by a further reduction in the THMFPF compared to the conventional only coagulation-flocculation-settling process.
Keywords
PAClTrihalomethaneshydrophilic acidSpecific UV absorbanceTHMTPHATHMFPHPOADEAESUVAWTPPACCFSDOCDBPDrinking waterraw waterUltraviolet absorbancediethylaminoethyl celluloseDisinfection by-productsRefractive indexNatural organic matterNOMMolecular weightpolyaluminium chlorideWater treatment plantDissolved organic carbonPowdered activated carbon
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Health and Safety
Authors
Jon I. Álvarez-Uriarte, Unai Iriarte-Velasco, Noemà Chimeno-AlanÃs, Juan R. González-Velasco,