Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
580682 | Journal of Hazardous Materials | 2010 | 5 Pages |
Abstract
Norfloxacin, doxycycline and mefenamic acid have been photolysed with UV-C radiation (254 nm) in the presence and absence of inorganic peroxides (hydrogen peroxide or sodium monopersulfate). Quantum yields in the range (1.1-4.5) Ã 10â3 mol Einsteinâ1 indicate the low photo-reactivity of these pharmaceuticals. Inorganic peroxides considerably enhanced the contaminants conversion, although no appreciable mineralization could be obtained. A simplistic reaction mechanism for the hydrogen peroxide promoted experiments allowed for a rough estimation of the rate constant between hydroxyl radicals and norfloxacin (k > 1 Ã 109 Mâ1 sâ1), doxycycline (k > 1.5 Ã 109 Mâ1 sâ1) and mefenamic acid (k > 11.0 Ã 109 Mâ1 sâ1).
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Health and Safety
Authors
Javier Rivas, Olga Gimeno, Teresa Borralho, Maria Carbajo,